MJPEG is just a collection of JPEG images combined into a single file.
This means that frame captures look good (jpegs were designed for static images), but compression suffers as it cannot compress across frames.
MJPEG does compress across frames, but is meant to be viewed in motion, so stills don't look quite so crisp.
Settings can sometimes be tweaked so it's not quite so black and white as this, but that's the general theory.
"MJPEG is an outdated and inefficient codec, whose main advantages are low processor overhead, ease of editing, ease of implementation by developers using existing JPEG algorithms or libraries, and broad compatibility."
http://en.wikipedia.org/wiki/Mjpeg
Duncan